An efficient ligand-free method for the transfer hydrogenation of ketones and aldehydes catalyzed by different complexes


Yasar S., Cekirdek S., Akkus Tas N., YILDIRIM SARIKAYA S. , ÖZDEMİR İ.

TURKISH JOURNAL OF CHEMISTRY, cilt.37, ss.292-298, 2013 (SCI İndekslerine Giren Dergi) identifier

  • Cilt numarası: 37 Konu: 2
  • Basım Tarihi: 2013
  • Doi Numarası: 10.3906/kim-1211-29
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Sayfa Sayıları: ss.292-298

Özet

A very efficient ligand-free method was developed for the transfer hydrogenation of ketones and aldehydes catalyzed by different metal complexes. With this catalytic system, the catalytic performance and catalytic stability of different Ir, Ru, and Pd complexes were more favorable than those of the previously reported systems for transfer hydrogenation. This ligand-free catalytic system showed good stability and excellent activity even with lower catalyst concentrations for the ketones and aldehydes tested.