The synthesis and characterization of (MSalen/salophen/saldeta/salpy) [M=Fe(III) or Cr(III)] capped heteromultinuclear schiff bases-dioxime Ni(II) complexes: Their thermal and magnetic behaviours


UYSAL Ş. , KOÇ Z. E.

JOURNAL OF MOLECULAR STRUCTURE, cilt.1165, ss.14-22, 2018 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 1165
  • Basım Tarihi: 2018
  • Doi Numarası: 10.1016/j.molstruc.2018.03.101
  • Dergi Adı: JOURNAL OF MOLECULAR STRUCTURE
  • Sayfa Sayıları: ss.14-22

Özet

Chlorophenylglyoxime and Ligand Complexes ([M(Salen/Salophen)](2)O, [M(Saldeta/Salpy)Cl] shortened as LC, M = Fe(III) or Cr(III)) have been synthesized. 3,5-dicarboxyanilinophenylglyoxime (5) and 4-carboxyphenylhydrazinophenylglyoxime (6) have been synthesized with the reaction of chlorophenylglyoxime and 5-aminoisophtalalic acid or 4-hydrazinobenzoic acid. [M(Salen/Salophen/Saldeta/ Salpy)-3,5-dicarboxyanilinophenyl-glyoxime)] (7-14) or [M(Salen/Salophen)-4-carboxyphenylhydrazinophenylglyoxime)] (15-22) have been synthesized from (5) or (6) and LCs. The new heterotrinuclear and pentanuclear complexes (23-38) have been obtained from (7-22) and Ni(II) salt. Then, heteronuclear and BF2+ capped vic-dioxime complexes (39-54) have been synthesized. The complexes have been characterized as low-spin (S=1/2) distorted octahedral [Fe-III(Salen/Salophen)], high-spin (S = 5/2) distorted octahedral [Fe-III(Saldeta/Salpy)] and (S = 3/2) distorted octahedral [Cr-III(Salen/Salophen/Saldeta/Salpy)] bridged by COO- groups. The structure of all ligand and complexes were identified by using elemental analysis, thermal analyses, magnetic susceptibility, LC-MS, ICP-AES, H-1-NMR and FT-IR spectral data. (C) 2018 Elsevier B.V. All rights reserved.