Bis(mu-4-methylbenzoato)-kappa O-3,O':O;kappa O-3:O,O'-bis[aqua(4-methylbenzoato-kappa O-2,O') (nicotinamide-kappa N-1)cadmium]

DİNCEL Ö. , Tercan B., ÇİMEN E., NECEFOĞLU H., HÖKELEK T.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.68, 2012 (ESCI İndekslerine Giren Dergi) identifier identifier identifier

  • Cilt numarası: 68
  • Basım Tarihi: 2012
  • Doi Numarası: 10.1107/s1600536812047046
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS

Özet

In the dinuclear centrosymmetric title compound, [Cd-2(C8H7O2)(4)(C6H6N2O)(2)(H2O)(2)], the Cd-II ion is chelated by two carboxylate groups from 4-methylbenzoate anions, and is further coordinated by one nicotinamide and one water molecule; a carboxylate O atom from an adjacent 4-methylbenzoate anion bridges to the Cd-II ion, completing the irregular coordination sphere of the seven ligand atoms. In the crystal, intermolecular O-H center dot center dot center dot O, N-H center dot center dot center dot O and weak C-H center dot center dot center dot O hydrogen bonds link the molecules into a three-dimensional network. The methylbenzene moiety of one bridging 4-methylbenzoate anion is disordered over two orientations of equal occupancy.