Hydrothermal liquefaction of microalgae with metal halides for bio-crude production


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AKALIN M. K.

JOURNAL OF THE FACULTY OF ENGINEERING AND ARCHITECTURE OF GAZI UNIVERSITY, cilt.34, ss.846-853, 2019 (SCI İndekslerine Giren Dergi)

  • Cilt numarası: 34 Konu: 2
  • Basım Tarihi: 2019
  • Doi Numarası: 10.17341/gazimmfd.460484
  • Dergi Adı: JOURNAL OF THE FACULTY OF ENGINEERING AND ARCHITECTURE OF GAZI UNIVERSITY
  • Sayfa Sayısı: ss.846-853

Özet

In this study, the microalgae Spirulina was converted into bio-crudes under hydrothermal conditions. In the first part (non-additive experiments), the effects of different hydrothermal processing temperatures (ranged from 250 to 375 degrees C), different initial pressures (ranged from 1 to 4 MPa) and residence times (ranged from 30 to 120 min) on the bio-crude and solid residue yields were investigated. The highest bio-crude yield was about 36wt% and obtained at 350 degrees C with a residence time of 30 min and an initial pressure of 1 MPa. In second part (experiments with metal halide additives), the effect of metal halides (CsCl, CsCl-KCl, CsCl-NaCl, CsCl-ZnCl2, and CsCl-SnCl2) on the bio-crude yields and compositions were investigated. The metal halides used in the experiments were ineffective on bio-crude yields. The highest diesel fuel content of the bio-crude was 78wt% and obtained from the run with CsCl-NaCl. The use of catalysts slightly increased the carbon content and slightly decreased the oxygen content in bio-crudes in comparison with the run without a catalyst. The key compounds in bio-crudes were nitrogen containing compounds including amines, amides, pyrrolidines, indoles, and pyrazines. The highest heating value of the bio-crude was about 33 MJ/kg and obtained in the runs with CsCl and CsCl-SnCl2.